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The preferred oil type for the 2014 Mercedes E350 is 0w-40 full synthetic engine oil. When changing the oil, ensure that the vehicle has been turned off and parked for a few hours to prevent burns from hot oil. Locate the oil pan and drain plug beneath the car's engine compartment, place a bucket under the plug, and remove it to allow the oil to drain into the pan. Wait until the dripping stops, usually around an hour. Reattach the drain plug, find the intake port on the oil pan, and fill it up using a funnel. Avoid overfilling to prevent leaks and oil burn off, a bit below full is okay. Close the port, clean any spilled oil, and you are done.
The 2014 Mercedes E350 calls for using Castrol Edge 0W-40 fully synthetic engine oil.