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For the 2008 Mercedes Benz R350, the recommended oil types are 0W-30 and 0W-40. If you are in a place where it's colder than -13°F, then you should use 5W-30, 5W-40, or 5W-50. For temperatures above -4°F, 10W-30, 10W-40, 10W-50, or 10W-60 are suitable. Areas with temperatures above 5°F should go for 15W-30, 15W-40, or 15W-50 oils. And if it's above 23°F, opt for 20W-40 or 20W-50. Remember, the vehicle's oil capacity is 8.5 US quarts. Follow the owner's manual for oil change intervals, and check and refill the oil level weekly.
In 2008, the recommended oil for a Mercedes R350 is Pentosin Synthetic Motor Oil 5W-30, sold in 1-liter bottles.